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氢化亚铜 (10309 views - Material Database)

氢化亚铜(化学式:CuH)是铜的二元氢化物。Cu-H键很弱因此这种化合物是不稳定的。硫酸铜与次磷酸钠在少量硫酸存在的条件下反应得到这种红色沉淀。它受热就分解为金属铜和氢气。X射线衍射实验已经测定了它的晶体结构。它与三苯基膦的加合物是有机化学中的斯瑞克试剂。
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氢化亚铜

氢化亚铜

氢化亚铜
IUPAC名
氢化亚铜
识别
PubChem 3335333
ChemSpider 2582262
SMILES
性质
化学式 HCu
摩尔质量 64.55 g·mol−1
精确质量 63.937426111 g mol-1
若非注明,所有数据均出自一般条件(25 ℃,100 kPa)下。

氢化亚铜化学式:CuH)是铜的二元氢化物。Cu-H键很弱因此这种化合物是不稳定的。[1][2]硫酸铜次磷酸钠在少量硫酸存在的条件下反应得到这种红色沉淀。它受热就分解为金属铜和氢气。X射线衍射实验已经测定了它的晶体结构。[3]它与三苯基膦的加合物是有机化学中的斯瑞克试剂英语Stryker's reagent

参考资料

  1. ^ Hydrides of the Main-Group Metals: New Variations on an Old Theme Simon Aldridge , Anthony J. Downs Chem. Rev., 2001, 101 (11), pp 3305–3366 doi:10.1021/cr960151d
  2. ^ Laboratory Methods of Inorganic Chemistry Wilhelm Biltz Heinrich
  3. ^ The crystal structure of copper hydride J. A. Goedkoop and A. F. Andresen Acta Cryst. (1955). 8, 118-119 doi:10.1107/S0365110X55000480

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