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Diisobutyl phthalate (3552 views - Material Database)

Diisobutyl Phthalate (DIBP) is prepared by esterification process of isobutanol and phthalic anhydride. Its structural formula is C6H4(COOCH2CH(CH3)2)2. DIBP is an odorless plasticizer and has excellent heat and light stability. It is the lowest cost plasticizer for cellulose nitrate. DIBP has lower density and freezing point than DBP (dibutyl phthalate, CAS No.: 84-74-2). It has similar properties as dibutyl phthalate and can be used as a substitute for it. Its refractive index is 1.488 – 1.492 (at 20 °C, D).
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Diisobutyl phthalate

Diisobutyl phthalate

Diisobutyl phthalate
Diisobutyl phthalate
Names
Preferred IUPAC name
Bis(2-methylpropyl) benzene-1,2-dicarboxylate
Other names
Diisobutyl phthalate
Diisobutyl ester of phthalic acid
1,2-benzenedicarboxylic acid bis(2-methylpropyl)ester
Di(isobutyl) 1,2-benzenedicarboxylate
DIBP
DiBP
Palatinol IC
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.001.412
EC Number 201-553-2
KEGG
RTECS number TI1225000
Properties
C16H22O4
Molar mass 278.35 g/mol
Appearance Colorless viscous liquid
Density 1.038 g/cm3
Melting point −37 °C (−35 °F; 236 K)
Boiling point 320 °C (608 °F; 593 K)
1 mg/l at 20 °C
log P 4.11
Vapor pressure 0.01 Pa at 20 °C
Hazards
Main hazards Harmful (Xn), Dangerous for the environment (N)
R-phrases (outdated) R50/53;R62;R63
S-phrases (outdated) S36/37;S61
NFPA 704
Flammability code 1: Must be pre-heated before ignition can occur. Flash point over 93 °C (200 °F). E.g., canola oilHealth code 0: Exposure under fire conditions would offer no hazard beyond that of ordinary combustible material. E.g., sodium chlorideReactivity code 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g., liquid nitrogenSpecial hazards (white): no code
1
0
0
Flash point 185 °C (365 °F; 458 K) c.c.
400 °C (752 °F; 673 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Diisobutyl Phthalate (DIBP) is prepared by esterification process of isobutanol and phthalic anhydride. Its structural formula is C6H4(COOCH2CH(CH3)2)2.

DIBP is an odorless plasticizer and has excellent heat and light stability. It is the lowest cost plasticizer for cellulose nitrate. DIBP has lower density and freezing point than DBP (dibutyl phthalate, CAS No.: 84-74-2). It has similar properties as dibutyl phthalate and can be used as a substitute for it. Its refractive index is 1.488 – 1.492 (at 20 °C, D).

Health issues

The concentration of a metabolite of DIBP (Mono-isobutyl phthalate or MIBP) has been steadily increasing in the urine of Americans over the period 1999-2008.[1] Prenatal maternal exposure is associated with substantial harm to intellectual development in children.[2]

Products in Taiwan made from Hebo Natural Products Limited (禾博天然產物有限公司) of China contained ginger contaminated with DIBP, some 80,000 nutritional supplement capsules made with imported ginger powder were seized by the Public Health Department of Taiwan in June 2011.[3] In addition, soybean extract and olive leaf extract, both in powder form, were contaminated with DIBP and DBP. Concentration of DIBP in the ginger extract powder was found to be 33,100 parts per million (ppm), that of DIBP in the soybean extract powder, 41 ppm, and that of DIBP and DBP in the olive leaf extract powder, 768 ppm and 441 ppm, respectively.[4]

See also



This article uses material from the Wikipedia article "Diisobutyl phthalate", which is released under the Creative Commons Attribution-Share-Alike License 3.0. There is a list of all authors in Wikipedia

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