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At a cube, an edge shall be rounded.
Select adjacent faces of the edge to be rounded or alternatively the edge itself.
Select the Fillet option and in the input field, enter the desired Radius.
In 3D History, on the blend feature, by clicking on Edit..., you can call the dialog anytime.
You can adjust values subsequently or switch from Fillet to Chamfer.
Example in 2D: Chamfer with setting "Distance 1" =3 and "Distance 2" = 1 at a cube with edge length = 10